Download Alkaline-Earth Metal Compounds: Oddities and Applications by Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder PDF

By Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder (eds.)

The sequence issues in Organometallic Chemistry offers serious overviews of analysis leads to organometallic chemistry. As our figuring out of organometallic constitution, houses and mechanisms raises, new methods are opened for the layout of organometallic compounds and reactions adapted to the desires of such varied parts as natural synthesis, scientific study, biology and fabrics technology. therefore the scope of insurance contains a large diversity of themes in natural and utilized organometallic chemistry, the place new breakthroughs are being accomplished which are of importance to a bigger clinical viewers. the person volumes of subject matters in Organometallic Chemistry are thematic. evaluate articles are commonly invited through the amount editors.

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Extra info for Alkaline-Earth Metal Compounds: Oddities and Applications

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3 Synthesis of Diarylcalcium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Alternative Routes to Post-Grignard Reagents . . . . . . . . . . . . . . . . . . . . 3 Properties of Post-Grignard Reagents . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 NMR Studies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Yan K, Upton BM, Ellern A, Sadow AD (2009) J Am Chem Soc 131:15110 211. Quisenberry KT, White RE, Hanusa TP, Brennessel WW (2010) New J Chem 34:1579 212. Chmely SC, Carlson CN, Hanusa TP, Rheingold AL (2009) J Am Chem Soc 131:6344 213. Jochmann P, Dols TS, Spaniol TP, Perrin L, Maron L, Okuda J (2009) Angew Chem Int Ed 48:5715 214. Harvey MH, Hanusa TP, Young VGJ (1999) Ang Chem Int Ed 38:217 215. McCormick MJ, Williams RA, Levine LJ, Hanusa TP (1988) Polyhedron 7:725 216. Williams RA, Tesh KF, Hanusa TP (1991) J Am Chem Soc 113:4843 217.

So far, the only dimetalated derivative formed by a Ca-Grignard-analog reaction is [Me2Si{C6H4[–p-CaI(thf)4}2] [95], in which the metalated arene rings are separated by an SiMe2 group prohibiting electronic communication between the two post-Grignard moieties. The higher homologues of calcium, strontium, and barium are reactive in the direct synthesis, too, yielding arylstrontium and arylbarium halides, but due to their even higher reactivity, the primary products of those reactions resisted all efforts to be isolated as pure, well-defined compounds.

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